Recent surface forces apparatus experiments that measured the forces between two mica surfaces and a series of subsequent theoretical studies suggest the occurrence of universal underscreening in highly concentrated electrolyte solutions. We performed a set of systematic Atomic Force Spectroscopy measurements for aqueous salt solutions in a concentration range from 1 mM to 5 M using chloride salts of various alkali metals as well as mixed concentrated salt solutions (involving both mono- and divalent cations and anions), that mimic concentrated brines typically encountered in geological formations. Experiments were carried out using flat substrates and submicrometer-sized colloidal probes made of smooth oxidized silicon immersed in salt solutions at pH values of 6 and 9 and temperatures of 25 °C and 45 °C. While strong repulsive forces were observed for the smallest tip-sample separations, none of the conditions explored displayed any indication of anomalous long range electrostatic forces as reported for mica surfaces. Instead, forces are universally dominated by attractive van der Waals interactions at tip-sample separations of ≈2 nm and beyond for salt concentrations of 1 M and higher. Complementary calculations based on classical density functional theory for the primitive model support these experimental observations and display a consistent decrease in screening length with increasing ion concentration.
Tuesday 10 May 2022
More recent news
- Wed 21 Sep 2022Dr. S.J.A. De Beer and Prof.Dr. F.G. Mugele receive OTP grant from NWO-TTW
- Thu 31 Mar 2022Newly granted NWO-TTW project
- Tue 21 Dec 2021New PhD vacancy: CAPTURE, STORAGE AND MINERALIZATION OF CO2 IN PARTICLE SUSPENSIONS
- Mon 20 Dec 2021Congratulations Dr. Sachin Nair!
- Mon 13 Dec 2021Congratulations Dr. Beybin Ilhan!!