UTFacultiesTNWDept NEMResearchIMSNewsCreating efficient transparent p-type conductors

Creating efficient transparent p-type conductors Doping copper iodide with sulphur increases conductivity fivefold while staying transparent

Transparent conductors are essential for many devices, such as touch screens and solar cells. Copper iodide (CuI) can conduct electricity while staying see-through but is not as good as some other materials. Researchers from the University of Twente managed to improve the conductivity of CuI while keeping 75% of its transparency. By adding a tiny bit of sulphur, their new material moves us one step closer to fully transparent electronic devices.

There are two types of transparent conductors: p-type and n-type. The combination of both types makes it possible to create fully transparent devices. This can include innovations like see-through smartphones and, windows with incorporated translucent solar panels thereby blending aesthetics and functionality. But, so far, the p-types are falling short in terms of conductivity when compared to their n-type counterparts.

Adding sulphur

That’s why researchers are looking for ways to improve the p-type’s conductivity. They want to make them as good at conducting electricity as the n-types. The material CuI is a well-known p-type transparent conductor. Researchers from the University of Twente found out that adding a tiny bit of sulphur (3%) increased CuI’s conductivity by more than five times. The material significantly enhanced its ability to conduct electricity and lets almost all the light through. In fact, it's so good that it lets over 75% of the visible light pass through it.

Sulphur functionality

Thin films of CuI with sulphur are made with a process called pulsed laser deposition. Sulphur induces ‘defects’ in the material. These defects – or more specifically, copper vacancies – act like a source of free holes and contribute to the electrical conductivity of the material. While studying the sulphur-doped CuI, the researchers found dual functionality of sulphur. First of all, sulphur acts as a catalyst in promoting copper vacancies. Secondly, the high distribution of sulphur in grain boundaries leads to mixed phases in the material. Both make the material even better at conducting electricity. This discovery brings us closer to all sorts of gadgets and transparent electronic devices.

More Information

The first author of the study Adeem Saeed Mirza is a PhD candidate supervised by Prof. dr. Monica Morales Masis, part of the Inorganic Material Science chair (IMS; Faculty of S&T / MESA+ Institute) and defect studies were performed with collaborators at CCP (Faculty of S&T) and TU/Eindhoven. Their work led to a publication in the prestigious scientific journal Matter, entitled ‘The Role of Sulfur in Sulfur Doped Copper(I) Iodide p-type Transparent Conductors’. This work was financed by the NWO Start-Up grant

DOI: 10.1016/j.matt.2023.10.003

K.W. Wesselink - Schram MSc (Kees)
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